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Quantum light in curved low dimensional hexagonal boron nitride systems

机译:弯曲低维六方氮化硼系统中的量子光

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摘要

Low-dimensional wide bandgap semiconductors open a new playing field inquantum optics using sub-bandgap excitation. In this field, hexagonal boronnitride (h-BN) has been reported to host single quantum emitters (QEs), linkingQE density to perimeters. Furthermore, curvature/perimeters in transition metaldichalcogenides (TMDCs) have demonstrated a key role in QE formation. Weinvestigate a curvature-abundant BN system - quasi one-dimensional BN nanotubes(BNNTs) fabricated via a catalyst-free method. We find that non-treated BNNT isan abundant source of stable QEs and analyze their emission features down tosingle nanotubes, comparing dispersed/suspended material. Combining highspatial resolution of a scanning electron microscope, we categorize andpin-point emission origin to a scale of less than 20 nm, giving us a one-to-onevalidation of emission source with dimensions smaller than the laser excitationwavelength, elucidating nano-antenna effects. Two emission origins emerge:hybrid/entwined BNNT. By artificially curving h-BN flakes, similar QE spectralfeatures are observed. The impact on emission of solvents used in commercialproducts and curved regions is also demonstrated. The 'out of the box'availability of QEs in BNNT, lacking processing contamination, is a milestonefor unraveling their atomic features. These findings open possibilities forprecision engineering of QEs, puts h-BN under a similar 'umbrella' of TMDC'sQEs and provides a model explaining QEs spatial localization/formation usingelectron/ion irradiation and chemical etching.
机译:低维宽带隙半导体利用亚带隙激发开辟了一个新的运动场量子光学。在该领域,据报道六角形的硼氮化物(h-BN)承载着单个量子发射器(QE),从而将QE密度与周长联系起来。此外,过渡金属二卤化物(TMDC)中的曲率/周长已证明在QE形成中起关键作用。我们研究了一种曲率丰富的BN系统-通过无催化剂方法制备的准一维BN纳米管(BNNT)。我们发现未经处理的BNNT是稳定QE的丰富来源,并且可以比较单个分散的纳米管的发射特征,比较分散/悬浮的材料。结合扫描电子显微镜的高空间分辨率,我们将发射点归类并确定在小于20 nm的范围内,从而使发射源一对一验证,尺寸小于激光激发波长,从而阐明了纳米天线效应。出现了两个发射源:混合/交织的BNNT。通过人工弯曲h-BN薄片,观察到相似的QE光谱特征。还证明了对商品和弯曲区域中使用的溶剂排放的影响。 BNNT中QE的“开箱即用”的可用性,没有加工污染,是揭示其原子特征的里程碑。这些发现为QE的精确工程化打开了可能性,将h-BN置于TMDC的QE的“伞”下,并提供了一个模型解释电子/离子辐照和化学蚀刻对QE的空间定位/形成。

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